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Beilstein J. Org. Chem. 2019, 15, 2161–2169, doi:10.3762/bjoc.15.213
Graphical Abstract
Scheme 1: Reaction mechanisms of Huisgen cyclization catalyzed by Cu(I) and Ru(I).
Scheme 2: Synthesis and photochromism of bisthiazolyltriazoles.
Figure 1: Absorption spectral change of triazoles 1o–3o upon irradiation of 313 nm light in MeCN at 28 °C. Li...
Scheme 3: Wavelengths of absorption maxima of the closed forms of bisthienyletenes in hexane [36].
Scheme 4: Photochromism of closely related compounds.
Figure 2: Absorption spectral change of triazoles 1c–3c during the thermal back reaction after 313-nm light i...
Scheme 5: Bond length (a) (in Å) and Mulliken bond order (b) of 1c–3c obtained by DFT calculations. Top numbe...
Scheme 6: Possible reaction mechanism of thermal ring opening of the closed forms.